Poisonous medicinal substances (list A) are stored under lock and key in iron cabinets, or in metal boxes (safe), on which the inscription “ Venena"(Poisonous).

And especially poisonous medicinal substances (morphine, atropine sulfate, etc.) are stored in internal, locked compartments of safes and cabinets.

Typically, these substances in prescriptions are written in miles or centigrams. On the inside of the door of a safe or cabinet, there should be a list of toxic medicinal substances contained inside, indicating the highest one-time. Poisonous medicinal substances are subject to quantitative accounting in special journals.

The same cabinet (safe) contains everything necessary for weighing, measuring and mixing these substances (scales, weights, funnels, cylinders, measuring fingers, etc.). Rod-glasses design: black background, white letters.

In rooms where poisonous medicinal substances are stored, the windows are reinforced with iron bars, and the doors are upholstered with iron. With the permission of higher organizations, it is possible to store these substances in the same room with other medicinal substances. Cabinets and safes must be locked with keys that are at the head of the pharmacy (responsible for the pharmacy), or at the pharmacist-technologist.

Work with poisonous medicinal substances (List A).

Toxic substances are weighed out to the pharmacist by the pharmacist-technologist. To get the substances into operation, you must fill out the appropriate documentation.

N-acetylanthranilic acid
Aconite
Aconitine
Aceclidine (3-quinuclidinyl acetate)
Brucin
Hyoscyamine base
Hyoscyamine camphor (L-tropyltropate (camphor))
Hyoscyamine sulfate (L-tropyltropate (sulfate))
Purified bee venom
Ricin
Metallic mercury
Thallium and its salts
Nickel tetracarbonyl
Tetraethyl lead and its mixtures with other substances (ethyl liquid and others), except for leaded gasolines
Zinc phosphide
White phosphorus (yellow phosphorus)
Cyanplav
Cyclone
Qinghoning

Free Download the Complete List of Poisonous Substances can !

This is how the storage and work with toxic substances occurs, I hope you have stored in your memory the information written in this article. Next, we will touch on the potent medicinal substances of list B, do not miss it! Don't forget to rate articles and comment, Thanks for your attention!

│ │ average concentration │ steel (for example, 12X18M9T) │ ├───┼────────────────────┼─────────── ────────────────────────────┤ │2 │Sulfuric acid │Corrosion-resistant barrels and tanks │ │ steel (for example, 12X18M9T) │ ├───┼─────────────────────┼────────────────────── ───────────────┤ │3 │ Hydrochloric acid │ Steel rubberized drums and │ │ any concentration │ tanks │ ├───┼─────────── ──────────┼────────────────────────────────────┤ │4 │Fluoric acid (fluorine-│Ebony cans with a capacity of up to 20 liters, │ │ │hydrogen) acid │ polyethylene cylinders with a capacity of up to │ │ │ 50 liters │ ├───┼──────────── ─────────┼────────────────────────────────────┤ 5 │ Caustic soda │ Iron drums, barrels │ └───┴────────────────────┴───────────── ─────────────────────────┘

Notes. 1. Nitric and sulfuric acids in quantities up to 40 liters can be stored in glass bottles.

2. On containers with caustic soda (caustic) there should be an inscription "Dangerous - caustic".

7.8.4. Containers with chemicals must have clear inscriptions, labels with the name of the substance, GOST and the number of technical conditions.

7.8.5. It is prohibited to store corrosive substances in basements, semi-basements and upper floors of multi-storey buildings.

7.8.6. Bottles with acids should be installed in groups (no more than 100 bottles in a group) in two or four rows with aisles between groups at least 1 m wide.

7.8.7. It is forbidden to install bottles with acid on racks in more than two tiers in height. In this case, the shelves of the second tier should be at a height of no more than 1 m from the floor.

7.8.8. Do not place bottles with acid near heating devices.

7.8.9. When pouring acid from a bottle, special devices should be used to gradually tilt the bottle and a nozzle to prevent acid spills and splashing.

7.8.10. When transporting and storing acids and other corrosive liquids, only conical bottles should be used, which must be tightly packed in conical baskets or wooden crates, on the bottom and sides of which straw or shavings should be laid.

7.8.11. When storing nitric acid, straw or shavings should be soaked in a solution of calcium chloride or magnesium chloride.

7.8.12. Care must be taken when opening containers with acid, because the emission of vapors and gases accumulated in the upper part of the tank is possible.

7.8.13. In order to avoid bursting of the bottles during thermal expansion, they should be filled no more than 0.9 of their volume.

7.8.14. Filled bottles must be carried by at least two persons using a special stretcher. It is allowed to lift baskets with bottles with acid by the handles only after a preliminary check of the integrity and reliability of the bottom and handles of the basket.

7.8.15. Transportation of containers with acid is allowed only on specially equipped trolleys.

7.8.16. When transporting caustic substances in bottles, the shavings for their packing in crates must be impregnated with a fire-resistant compound. Bottles should be no more than 0.9 times full and carefully sealed.

7.8.17. The transportation of acids should be carried out in special tanks with an internal acid-resistant lining.

7.8.18. Acids and other corrosive liquids in small (up to 1 kg) packaging should be transported in appropriate packaging that protects the container from breakage and falling out. Glass containers with corrosive substances should be tightly sealed and packed in wooden or plywood boxes using lightweight packaging material. The weight of such boxes should not exceed 50 kg.

7.8.19. In storage warehouses and in places where acids are used, there should be reserve tanks for emergency draining of acids.

7.8.20. In rooms where chemicals and solutions are stored, instructions for their safe handling should be posted in visible and accessible places.

7.8.21. It is forbidden to put containers with potent toxic substances (SDYAV) on top of each other and in bulk. SDYAV packed in iron drums may be installed in two tiers in height.

7.8.22. Joint storage of poisons with other materials, as well as poisons of various categories is not allowed.

7.8.24. For the transportation of SDYAV within the organization, an admission order must be issued as for the production of work of special danger.

7.8.25. Transportation of SDYAV is allowed only in a serviceable, closed container with an indication of the name of pesticides and the inscription "POISON".

7.8.26. Delivery of SDYAV during rain or snow should be carried out with a tarpaulin cover, which should be stored in a warehouse in a closed box for such cases.

7.8.27. Acceptance of SDYAV for storage in the warehouse should be carried out only by the employee responsible for their storage, and in the presence of the employee responsible for their transportation.

7.8.28. Acceptance of SDYAV to the warehouse should be made on the day the cargo arrives at the organization.

If the cargo arrived at night, then it is accepted at the warehouse in the morning.

Prior to acceptance to the warehouse, the cargo with SDYAV in a sealed form must be guarded.

7.8.29. Before accepting cargo from SDYAV to the warehouse, the employee responsible for storing SDYAV must carefully check the correctness and integrity of the packaging and labeling of each individual piece of cargo.

7.8.30. When unloading poisons, the employee responsible for storing the SDYAV must ensure that precautions are taken so that the container with SDYAV is not damaged, not hit, thrown, not dragged, etc.

7.8.31. If there are no standard stencils on the container, the warehouse manager (storekeeper) must restore them and note this in the acceptance certificate.

7.8.32. If a container malfunction is detected, poisons in a faulty container (without overfilling) should be transferred to a new, clean container of a larger size and hermetically sealed with a lid. All work must be carried out in a gas mask.

7.8.33. Outside working hours, the room where poisons are stored must be closed, sealed (sealed) and put under guard.

7.8.34. Entering the poison storage room after a break in work for more than one hour is allowed only after the ventilation is turned on and its continuous operation for at least 30 minutes.

7.8.35. When storing cyanide salts, one should be guided by the sanitary rules for the design and maintenance of warehouses for storing potent toxic substances.

7.8.36. Cyanide salts should be stored in isolated, non-combustible heated rooms, access to which is allowed only to specially designated personnel.

7.8.37. Storage rooms for cyanide salts must be dry and equipped with effective ventilation. In a room separate from the storage room, washbasins with hot and cold water, wardrobes for overalls, special footwear and other personal protective equipment, a first-aid kit, and a telephone should be installed.

7.8.38. In the pantry for storing cyanide salts, there must always be scales, weights, a tool for opening containers, a scoop, a brush, a container for collecting waste, which is prohibited to use or take out to other premises, and must be neutralized without delay.

7.8.39. A small tightly closing hole should be arranged in the door of the pantry for storing cyanide salts to determine the presence of hydrogen cyanide (hydrocyanic acid) in the room air, the presence of which is determined by litmus paper introduced into the room through the specified opening before opening the door.

7.8.40. If the presence of hydrogen cyanide is detected in the air of the pantry, the room must be ventilated and the air sample repeated.

The entrance to the pantry room, where cyanide salts are stored, is allowed only if there is no reaction to hydrogen cyanide in the produced samples.

7.8.41. In emergency situations, the entrance to the cyanide storage pantry is allowed only in a gas mask.

7.8.42. Opening of containers, packaging or hanging of cyanide salts should be carried out by specially trained workers - storekeepers.

At the same time, strict accounting of the consumption and arrival of cyanide salts with registration in a special journal should be kept.

7.8.43. Work with cyanide salts must be carried out with the use of personal protective equipment - rubber gloves, gas masks.

7.8.44. Opening of containers with cyanide salt should be done with a non-impact tool in a fume hood.

7.8.45. Spills of cyanide salts must be carefully collected and put into a special metal sealable container for waste, and the place where the spill was must be neutralized.

7.8.46. Dust collected from the equipment must be neutralized in specially designated places.

7.8.47. For storage of nitrate, only metal containers with a tight-fitting lid should be used. Storage of nitrate in bags, wooden containers is prohibited.

7.8.48. It is necessary to store boron-containing substances in dry and heated rooms, since these substances are highly hygroscopic.

To category: Plant pests and diseases

Basic rules for storing poisons and precautions when working with them

1. Poisons are stored in specially designated rooms under lock and key; the key to the warehouse is with the person in charge; unauthorized persons are prohibited from entering the poison storage facility.

2. The room must be dry with a working roof.

3. Poisons are placed on the shelves; the container must contain labels with the name of the poison, batch numbers, net and gross weights, as well as safety notices.

4. Poisons entering the warehouse are included in a special book and issued against a receipt to persons who are entrusted with carrying out chemical activities.

5. Poisons are issued only at the direction of the head of the institution or an official substitute for him.

6. It is forbidden to store food and foreign objects in the warehouses of poisons.

7. The warehouse must have: a washstand, a towel, soap, protective clothing, scales and weights, as well as a first-aid kit with antidotes, supplied with special instructions.

8. Persons working with poisons should be familiar with the properties of poisons, their handling and precautions during work.

9. In the warehouse, an instruction with the rules for handling poisons is posted in a conspicuous place.

10. Workers with poisons should be provided with gowns, gloves, goggles, respirators, and when working with gaseous substances - gas masks.

11. While working with poisons, do not eat or smoke. At the end of the work, be sure to wash your hands and face.

12. Teenagers, pregnant and breastfeeding women are not allowed to work with poisons.

13. After the end of the work, all the remains of the poison should be buried in the ground in order to avoid poisoning, and the container should be thoroughly washed and handed over to the warehouse; the workers' clothes are thoroughly shaken out, respirators and goggles are cleaned of dust or washed.

14. When processing flower plants in parks of culture and recreation, squares and other populated areas, measures must be taken to prevent the possibility of poisoning people and animals.

15. Treatment of plants in settlements is carried out early in the morning or at night. The processed objects should be closed to visitors during processing and protected by designated persons during and after processing, depending on the poison used. Safety notices must be made on the treated areas.

- Basic rules for storing poisons and precautions when working with them

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POSITION- LABOR PROTECTION DURING STORAGE OF MATERIALS POT RO-14000-007-98 (approved by the Ministry of Economy of the Russian Federation from 25-02-98) (2020) Actual in 2018

7.8. Storage of toxic and corrosive chemicals

7.8.1. Depending on the physicochemical properties and the degree of potential hazard, poisonous and caustic chemicals should be stored in special warehouses or in specially equipped areas.

7.8.2. Most chemical materials should be stored separately as they can ignite on contact with each other, produce explosive mixtures, release toxic gases, etc. Data on the incompatibility of storage of chemical materials are given in table. 5.

Table 5

CHEMICAL MATERIALS INCOMPATIBLE FOR SHARED STORAGE

Chemical name	Substances unacceptable for joint storage
Activated carbon	Calcium hydrochloride and all oxidizing products
Ammonia (gas)	Mercury, chlorine, calcium hydrochloride, iodine, bromine, hydrofluoric acid (anhydrous)
Ammonium nitric acid (ammonium nitrate)	Acids, powdered metals, flammable liquids, chlorates, nitrates, sulfur compounds, flammable micronized organic products
Acetylene	Chlorine, bromine, copper, fluorine, silver, mercury
Barium peroxide	Ethyl and methyl alcohols, acetic acid, acetic anhydride, basic aldehydes, carbon disulfide, glycerin, ethylene glycol, methyl acetate, furfural
Bromine	Ammonia, acetylene, butane, methane, propane (or other petroleum gases), hydrogen, turpentine, benzene, finely divided metal powders
Chlorine dioxide	Ammonia, phosphates, sulfur dioxide, methane, iodine, mineral and organic acids, acetylene, ammonia, ammonia water, hydrogen
Metallic potassium
Perchloric acid	Acetic anhydride, bismuth and its alloys, alcohol, paper, wood
Copper	Acetylene, hydrogen peroxide
Metallic sodium	Carbon tetrachloride, carbon dioxide, water
Hydrogen peroxide	Copper, chromium, iron, numerous metals and their salts, alcohol, acetone, organic products, aniline, nitromethane, all flammable liquids and flammable substances
Potassium permanhydrate	Glycerin, ethylene glycol, benzaldehyde, sulfuric acid
Mercury	Acetylene, oxyhydrogen, ammonia (gas)
Silver	Acetylene, concentrated nitric acid, ammonia compounds, oxalic acid, tartaric acid
Sulphuric acid	Potassium chlorate, potassium perchlorate, permanganate and other compounds with light metals similar to sodium, lithium
Hydrogen sulfide	Nitric acid, oxidizing gases
Hydrocarbons (butane, propane, benzene, volatile solvents, turpentine, etc.)	Fluorine, bromine, chromic acid, oxidants
Acetic acid	Chromic acid, nitric acid, ethylene glycol, perchloric acid, peroxides, permanganates
Fluorine	Must be isolated from all active chemical materials
Hydrofluoric acid (anhydrous)	Acetic acid, aniline, chromic acid, hydrocyanic acid, hydrogen sulfide, flammable liquids and gases

CONTAINERS FOR STORING POISONOUS AND CORROSIVE CHEMICALS

N p / p	Substance	Container for storing it
1	Nitric acid: Any concentration of medium concentration	Aluminum drums and tanks Drums and tanks made of corrosion-resistant steel (for example, 12X18M9T)
2	Sulphuric acid	Barrels and tanks made of corrosion-resistant steel (for example, 12X18M9T)
3	Hydrochloric acid of any concentration	Steel rubberized barrels and tanks
4	Hydrofluoric (hydrofluoric) acid	Ebonite cans with a capacity of up to 20 l, polyethylene cylinders with a capacity of up to 50 l
5	Sodium hydroxide	Iron drums, barrels

7.8.6. Bottles with acids should be installed in groups (no more than 100 bottles in a group) in two or four rows with aisles between groups at least 1 m wide.

7.8.7. It is forbidden to install bottles with acid on racks in more than two tiers in height. In this case, the shelves of the second tier should be at a height of no more than 1 m from the floor.

7.8.8. Do not place bottles with acid near heating devices.

7.8.9. When pouring acid from a bottle, special devices should be used to gradually tilt the bottle and a nozzle to prevent acid spills and splashing.

7.8.10. When transporting and storing acids and other corrosive liquids, only conical bottles should be used, which must be tightly packed in conical baskets or wooden crates, on the bottom and sides of which straw or shavings should be laid.

7.8.11. When storing nitric acid, straw or shavings should be soaked in a solution of calcium chloride or magnesium chloride.

7.8.12. Care must be taken when opening containers with acid, because the emission of vapors and gases accumulated in the upper part of the tank is possible.

7.8.13. In order to avoid bursting of the bottles during thermal expansion, they should be filled no more than 0.9 of their volume.

7.8.14. Filled bottles must be carried by at least two persons using a special stretcher. It is allowed to lift baskets with bottles with acid by the handles only after a preliminary check of the integrity and reliability of the bottom and handles of the basket.

7.8.15. Transportation of containers with acid is allowed only on specially equipped trolleys.

7.8.16. When transporting caustic substances in bottles, the shavings for their packing in crates must be impregnated with a fire-resistant compound. Bottles should be no more than 0.9 times full and carefully sealed.

7.8.17. The transportation of acids should be carried out in special tanks with an internal acid-resistant lining.

7.8.18. Acids and other corrosive liquids in small (up to 1 kg) packaging should be transported in appropriate packaging that protects the container from breakage and falling out. Glass containers with corrosive substances should be tightly sealed and packed in wooden or plywood boxes using lightweight packaging material. The weight of such boxes should not exceed 50 kg.

7.8.19. In storage warehouses and in places where acids are used, there should be reserve tanks for emergency draining of acids.

7.8.20. In rooms where chemicals and solutions are stored, instructions for their safe handling should be posted in visible and accessible places.

7.8.21. It is forbidden to put containers with potent toxic substances (SDYAV) on top of each other and in bulk. SDYAV packed in iron drums may be installed in two tiers in height.

7.8.22. Joint storage of poisons with other materials, as well as poisons of various categories is not allowed.

7.8.24. For the transportation of SDYAV within the organization, an order must be drawn up - admission as for the production of work of special danger.

7.8.25. Transportation of SDYAV is allowed only in a serviceable, closed container with an indication of the name of pesticides and the inscription "POISON".

7.8.26. Delivery of SDYAV during rain or snow should be carried out with a tarpaulin cover, which should be stored in a warehouse in a closed box for such cases.

7.8.27. Acceptance of SDYAV for storage in the warehouse should be carried out only by the employee responsible for their storage, and in the presence of the employee responsible for their transportation.

7.8.28. Acceptance of SDYAV to the warehouse should be made on the day the cargo arrives at the organization.

If the cargo arrived at night, then it is accepted at the warehouse in the morning.

Prior to acceptance to the warehouse, the cargo with SDYAV in a sealed form must be guarded.

7.8.29. Before accepting cargo from SDYAV to the warehouse, the employee responsible for storing SDYAV must carefully check the correctness and integrity of the packaging and labeling of each individual piece of cargo.

7.8.30. When unloading poisons, the employee responsible for storing the SDYAV must ensure that precautions are taken so that the container with SDYAV is not damaged, not hit, thrown, not dragged, etc.

7.8.31. If there are no standard stencils on the container, the warehouse manager (storekeeper) must restore them and note this in the acceptance certificate.

7.8.32. If a container malfunction is detected, poisons in a faulty container (without overfilling) should be transferred to a new, clean container of a larger size and hermetically sealed with a lid. All work must be carried out in a gas mask.

7.8.33. Outside working hours, the room where poisons are stored must be closed, sealed (sealed) and put under guard.

7.8.34. Entering the poison storage room after a break in work for more than one hour is allowed only after the ventilation is turned on and its continuous operation for at least 30 minutes.

7.8.35. When storing cyanide salts, one should be guided by the sanitary rules for the design and maintenance of warehouses for storing potent toxic substances.

7.8.36. Cyanide salts should be stored in isolated, non-combustible heated rooms, access to which is allowed only to specially designated personnel.

7.8.37. Storage rooms for cyanide salts must be dry and equipped with effective ventilation. In a room separate from the storage room, washbasins with hot and cold water, wardrobes for overalls, special footwear and other personal protective equipment, a first-aid kit, and a telephone should be installed.

7.8.38. In the pantry for storing cyanide salts, there must always be scales, weights, a tool for opening containers, a scoop, a brush, a container for collecting waste, which is prohibited to use or take out to other premises, and must be neutralized without delay.

7.8.39. A small tightly closing hole should be arranged in the door of the pantry for storing cyanide salts to determine the presence of hydrogen cyanide (hydrocyanic acid) in the room air, the presence of which is determined by litmus paper introduced into the room through the specified opening before opening the door.

7.8.40. If the presence of hydrogen cyanide is detected in the air of the pantry, the room must be ventilated and the air sample repeated.

The entrance to the pantry room, where cyanide salts are stored, is allowed only if there is no reaction to hydrogen cyanide in the produced samples.

7.8.41. In emergency situations, the entrance to the cyanide storage pantry is allowed only in a gas mask.

7.8.42. Opening of containers, packaging or hanging of cyanide salts should be carried out by specially trained workers - storekeepers.

At the same time, strict accounting of the consumption and arrival of cyanide salts with registration in a special journal should be kept.

7.8.43. Work with cyanide salts must be carried out with the use of personal protective equipment - rubber gloves, gas masks.

7.8.44. Opening of containers with cyanide salt should be done with a non-impact tool in a fume hood.

7.8.45. Spills of cyanide salts must be carefully collected and put into a special metal sealable container for waste, and the place where the spill was must be neutralized.

7.8.46. Dust collected from the equipment must be neutralized in specially designated places.

7.8.47. For storage of nitrate, only metal containers with a tight-fitting lid should be used. Storage of nitrate in bags, wooden containers is prohibited.

7.8.48. It is necessary to store boron-containing substances in dry and heated rooms, since these substances are highly hygroscopic.